Watching and sensing single molecules by confining light to the atom scale

Prof. Jeremy Baumberg, University of Cambridge, UK

15:00 Donnerstag, 02. November 2017

Prof. Jeremy Baumberg, University of Cambridge, UK


Coupling between plasmonic metal nano-components generates strongly red-shifted resonances combined with intense local field amplification on the nanoscale. This allows directly seeing molecules as well as excitations in semiconductors. We have recently explored plasmonic coupling which can be tuned dynamically, through reliable bottom-up self-assembly using the nanoparticle-on-mirror geometry (NPoM) [1-5]. We recently demonstrated how individual molecules can be strongly coupled to these ultralow volume plasmonic cavities as well as how they act as optomechanical constructs with enormously enhanced coupling.

We also demonstrate the possibility to track few molecules using the extreme enhancements. We are able to watch individual electrons hopping onto and off molecules in the gap, and watch redox processes in real time. These have encouraging prospective applications in (bio)molecular sensing as well as fundamental science. The ability to track and watch molecules interact and react opens up the ability to study chemistry molecule-by-molecule and potentially to control single reaction pathways.

[1] Nature 491, 574 (2012); Revealing the quantum regime in tunnelling plasmonics, 
[2] Nature Comm. 5, 4568 (2014); Threading plasmonic nanoparticle strings with light
[3] Nature Comm. 5, 3448 (2014); DNA origami based assembly of gold nanoparticle dimers for SERS detection
[4] Nature 535, 127 (2016); Single-molecule strong coupling at room temperature in plasmonic nanocavities
[5] Science 354, 726 (2016); Single-molecule optomechanics in picocavities

About DLS:

The Distinguished Lecturer Series (DLS) follows a colloquium format for a broad audience and will be followed by a reception to provide an opportunity for meeting the speaker.

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